Crystallography. Part 4: Crystal Forms Twinning презентация

Crystal Forms Habit: the general external shape of a crystal (e.g., prismatic, cubic, bladed...) Form: refers to a group of faces which have the same relation to the elements of

Слайд 1Lecture 11 (10/18/2006) Crystallography Part 4: Crystal Forms Twinning


Слайд 2Crystal Forms
Habit: the general external shape of a crystal (e.g., prismatic,

cubic, bladed...)

Form: refers to a group of faces which have the same relation to the elements of symmetry.

Crystals with higher degrees of symmetry tend to generate more form faces.

open
form

closed
form


Слайд 3Unique Attributes of Crystal Forms
NaCl
Faces of particular forms commonly share

unique physical or chemical attributes

Quartz

Anthophyllite

Pyrite


Слайд 4Form Indexes
defined by the Miller index (hkl) of the face in

the positive quadrant
enclosed in brackets {hkl}
a {100}, ρ {111}, c {001}

Tetragonal 4/m 2/m 2/m

a1

a2

c


Слайд 5Pyramids and Dipyramids
Prisms
Low Symmetry Forms


Слайд 6Trapezohedron, Scalehedron, Rhombehedron, Disphenoid


Слайд 7Isometric Forms


Слайд 8Twinning
Symmetrical intergrowth of two or more crystals related to a

symmetry operation (twin element) that is otherwise absent in a single crystal.
Twin elements includes mirrors, rotation axes (usually 2-fold) and roto-inversion that usually do not align with symmetry elements in the crystal.
Twin Laws define the twin element and its crystallographic orientation (twin planes are identified by its Miller index (hkl), twin axes are defined by a zone symbol [hkl]).

Слайд 9Twin Types
Potential
Twin Plane (111)
Mirror
Reflection
Composition
Plane
Contact Twins
Composition planes
correspond to twin planes

(mirrors)

Penetration Twins
Composition planes are irregular;
formed by rotational twin axis operation

Twin
Axes


Слайд 10Multiple Twins
Formed from 3 or more twinned crystals

Polysynthetic twins where

composition planes are parallel

Cyclic twins where composition planes are not parallel


Слайд 11Twin Laws in the Triclinic System
Albite Law
{010} twin plane
Albite combined
with

Pericline Law
[010] twin axis
results in “tartan twinning” in microcline (K-feldspar)


Слайд 12Twin Laws in the Monoclinic System
Note that twin planes do
not

align with mirror planes

Слайд 13Twin Laws in the Orthorhombic System
contact & cyclic
twinning
Contact or Penetrative??


Слайд 14Twin Laws in the Tetragonal System


Слайд 15Twin Laws in the Hexagonal System
{0112} is most common and may

produce single contact or polysynthetic twins

exception:
twin axis || C


Слайд 16Twin Laws in the Isometric System
Penetrative twins with twin axes parallel

to rotational axes

Слайд 17Next Lecture


No Lecture Next Week
Yeah!!!


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